Glossary entry

French term or phrase:

à front perdu

English translation:

until the solvent front is no longer visible

Added to glossary by Helen Genevier
May 5, 2008 13:58
16 yrs ago
1 viewer *
French term

front perdu

French to English Science Chemistry; Chem Sci/Eng TLC
"Placer la plaque dans une enceinte à chromatographie préalablement saturée par le solvant de migration. Faire migrer le solvant à front perdu."
Proposed translations (English)
3 +3 see explanation
5 +1 solvent front

Discussion

Helen Genevier (asker) May 5, 2008:
... it'd be good to know if there's a dedicated expression for this
Helen Genevier (asker) May 5, 2008:
This doc already uses the expression "front de solvent" as solvant front, and in most of the tests it says to develp until the solvent front has reached a distance of 15 cm, but in one case it is "à front perdu". I even have pictures of the chromatograms and on one the line "front de solvent" is drawn on and on the other it is labelled migration à front perdu at the top. It all points to Karen's answer, i.e. developed until the front has disappeared off the end of the plate.
Karen Tkaczyk May 5, 2008:
Hello Dr Jones. What do you mean by the 'front' is always 'perdu'? The answer to that may solve Helen's problem. I'm not familiar with a front being 'lost'.
:::::::::: (X) May 5, 2008:
Peer comments on this answer (and responses from the answerer)
agree Dr. Johanna Schmitt: that was my first thought, too...
How can you grant an agree when there's no answer given ??!!

Proposed translations

+3
7 mins
Selected

see explanation

Hi Helen,
I've never seen this before. All I can think of is that it means that you leave the plate in until the front runs all the way to the top of the plate, but I don't have anything to back that up with. If no-one else finds a solid answer I'll try to research it later and add a note.

--------------------------------------------------
Note added at 2 hrs (2008-05-05 15:59:45 GMT)
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I can't find a dedicated term Helen, neither in two textbooks I have on the subject nor online.
I've only come across this as being accidental - the point usually being to get the Rf as you know. I have let the solvent run off the top of the plate by accident many times though - we never had a specific came for that in the lab, that I recall (apart from 'idiot'!)
Note from asker:
Hi Karen, thanks. That's how I interpreted it too, but can only find 1 relevant ref in French and it's not enlightening.
Peer comment(s):

agree Dr. Johanna Schmitt : that was my first thought, too, but I can't back it up either, something like "until the front has run out of the plate and is not visible any more"
4 mins
Thanks
agree Isabelle Berquin : I couldn't find a dedicated term either but I agree with this interpretation - perhaps running the TLC longer than usual to resolve closely-migrating species, when Rf determination is not essential? Solvent migration will stop when it reaches the top.
11 hrs
Thanks
agree Drmanu49
2 days 6 hrs
Something went wrong...
4 KudoZ points awarded for this answer. Comment: "Thanks Karen and to everyone else for your helpful comments - I used until the solvent front is no longer visible"
+1
6 mins

solvent front

[PDF] solvent front (in chromatography)Format de fichier: PDF/Adobe Acrobat - Version HTML
solvent front (in chromatography). The front line of the eluent. O.B. 99. IUPAC Compendium of Chemical Terminology. 2nd Edition (1997)
www.iupac.org/goldbook/S05753.pdf - Pages similaires - À noter

paper chromatography- [ Traduire cette page ]An introduction to paper chromatography (including two way ... The left-hand diagram shows the paper after the solvent front has almost reached the top. ...
www.chemguide.co.uk/analysis/chromatography/paper.html - 17k - En cache - Pages similaires - À noter

Chromatography of amino acids- [ Traduire cette page ]Remove the paper from the apparatus, and use a pencil to mark the position of the solvent front. Up to 5 pieces of chromatography paper can be placed across ...
www.biotopics.co.uk/as/amino acid chromatography.html - 9k - En cache - Pages similaires - À noter
Peer comment(s):

neutral Karen Tkaczyk : I think the question is about 'perdu' not 'front'
1 min
Obviously, but the the 'front' is always 'perdu'...
agree Trinh Do : I've come across this term before
39 mins
Merci Trinh
Something went wrong...
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